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材料热力学 英文版PDF|Epub|txt|kindle电子书版本网盘下载
- 蒋青，文子著 著
- 出版社： 北京：高等教育出版社
- ISBN：9787040296105
- 出版时间：2011
- 标注页数：298页
- 文件大小：14MB
- 文件页数：315页
- 主题词：材料力学：热力学－高等学校－教材－英文
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图书目录
Chapter 1 Fundamentals of Thermodynamics1
1.1 Thermodynamics of Materials Science,Scope and Special Features of the Book1
1.2 Concepts of Thermodynamics5
1.3 Temperature and Zeroth Law of Thermodynamics10
1.4 First Law of Thermodynamics11
1.5 Entropy and Second Law of Thermodynamics20
1.6 General Thermodynamic Relationships24
1.7 Third Law of Thermodynamics32
References34
Chapter 2 Statistical Thermodynamics37
2.1 Basic Concepts38
2.2 Classical Statistic Thermodynamics of Independent Particles43
2.3 Energy Mode and Energy Levels47
2.4 Bose-Einstein and Fermi-Dirac Statistics52
2.5 Application of Quantum Statistics54
2.5.1 Spatial Configuration of Long Chain Polymers54
2.5.2 Statistical Thermodynamics of a Paramagnetic Crystal58
2.5.3 Negative Temperature63
References65
Chapter 3 Heat Capacity,Entropy,and Nanothermodynamics67
3.1 Heat Capacity67
3.1.1 Relations of Principal Heat Capacities67
3.1.2 Magnetic Heat Capacity69
3.1.3 Heat Capacity of Lattice Vibration of Solids71
3.1.4 Electronic Heat Capacity of Metals75
3.2 Entropy78
3.2.1 Positional Part of Melting Entropy and Its Evaluation83
3.2.2 Contribution of Vibrational Part of Melting Entropy of Semiconductors85
3.2.3 Electronic Component of Melting Entropy87
3.3 Nanothermodynamics93
3.4 Melting Thermodynamics95
3.4.1 A Melting Criterion95
3.4.2 Existing Models for Size-dependent Melting of Crystals96
3.4.3 Size-dependent Melting Thermodynamics of Crystals100
3.5 Cohesive Energy106
3.5.1 Size-dependent Cohesive Energy of Crystals106
3.5.2 Vacancy Formation Energy and Cohesive Energy of Clusters108
3.6 Size Effect on Bandgap of Ⅱ-Ⅵ Semiconductor Nanocrystals114
References116
Chapter 4 Phase Diagrams119
4.1 Gibbs Phase Rule and Phase Diagram of Unary System119
4.2 Clapeyron Equation in Condensed State Equilibria121
4.3 Solution,Partial Molar Properties and Chemical Potential126
4.4 Graphical Representation,Ideal and Regular Solutions129
4.5 Equilibrium Conditions of Phases and Phase Diagram of Binary Systems135
4.5.1 Complete Miscibility,Continuous Binary Solution Phase Diagram and Related Size Dependence136
4.5.2 Immiscibility-Two Mechanisms of Phase Transitions140
4.6 On Approximation of Gibbs Free Energy Change of Crystallization144
4.7 Bandgap Energy of Binary Nanosemiconductor Alloys148
References154
Chapter 5 Thermodynamics of Phase Transitions157
5.1 Thermodynamic Classification of Phase Transitions157
5.2 Landau and Ising Models for the Second-order Phase Transitions160
5.2.1 Landau Model160
5.2.2 Ising Model and its Applications162
5.2.3 Critical Exponent164
5.3 Thermodynamics of Martensitic and Bainite Transitions166
5.4 Glass Transition174
5.4.1 Freezing into Solid State:Glass Formation versus Crystallization174
5.4.2 Characteristic Properties of Glass Transition178
5.4.3 Size Effect on Glass Transition180
5.5 Ferromagnetic and Antiferromagnetic Phase Transitions of Nanocrystals184
5.5.1 Size-dependent Ordering Temperatures of Ferromagnetic and Antiferromagnetic Nanocrystals184
5.5.2 Thermal Stability in Exchange-biased FM/AFM Bilayers191
5.5.3 Ferroelectric Phase Transition of Nanocrystals197
5.5.4 Superconductive Phase Transition of Nanocrystals202
References205
Chapter 6 Thermodynamics of Interfaces207
6.1 Point Defect Thermodynamics208
6.2 Line Defects Thermodynamics211
6.3 Thermodynamics of Interfaces214
6.3.1 Thermodynamic Description of Surface Free Energy of Liquids and Solids215
6.3.2 Thermodynamics of Surface Stress and Intrinsic Stress216
6.3.3 Real Surface:Reconstruction and Relaxation221
6.3.4 Equilibrium of Fluid Droplets and Solid Particles225
6.3.5 Wulff Construction and Adsorption on Solid Surfaces229
6.4 Solid-liquid Interface Energy232
6.4.1 Bulk Solid-liquid Interface Energy and That at Melting Points232
6.4.2 Size Dependence of Solid-liquid Interface Energy239
6.4.3 Nucleus-liquid Interface Energy242
6.5 Solid-solid Interface Energy246
6.6 Solid-vapor Interface Energy or Surface Energy248
6.6.1 Bulk Surface Energy of Elementary Solids248
6.6.2 γsv0 of Several Ceramics with NaCl Structure257
6.6.3 Size-dependent Surface Energy of Solids261
6.7 Liquid-vapor Interface Energy or Surface Tension264
6.7.1 Bulk Surface Tension and Its Temperature Coefficient264
6.7.2 Determination of γLv0(Tm) and γ＇Lv0(Tm) Values and γLv0(T) and γ＇Lv0(T) Functions267
6.7.3 Size Dependence of Liquid-vapor Interface Energy275
6.8 Applications of Size-dependent Interface Energy278
6.8.1 Thermodynamic Phase Stability of Nanocarbons278
6.8.2 Static Hysteresis of Solid Transition of CdSe Nanocrystals284
6.8.3 Critical Layer Number and Critical Misfit of Epitaxial Grown Metallic Thin Films287
6.8.4 Reconstruction Possibility of fcc Metallic Surfaces at Room Temperature291
References293
Index295